Observing that F is a function of the co-ordinates expressing the state of the substance, we obtain for the variation of S with pressure at constant temperature, dS/dp (0 const) '=' 2 F/dedp =-0d 2 v/d0 2 (p const) (12) If the heat supplied to a substance which is expanding reversibly and doing external work, pdv, is equal to the external work done, the intrinsic energy, E, remains constant. [Please select]
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